PERFORMANCE ASSESSMENT OF BASALT STONE AS HEAT STORAGE MATERIAL FOR SOLAR THERMAL SYSTEM

 

M. ÖZBULDU   and   C. KARACA

Department of Biosystems Engineering, Faculty of Agriculture, Hatay Mustafa Kemal University, Hatay, Turkey.

Corresponding author; e-mail: ckaraca@mku.edu.tr

 

Cite this article as: 

Özbuldu, M., Karaca, C. (2022) “Performance assessment of basalt stone as heat storage material for solar thermal system”, Latin American Applied Research 52(3), pp 227-233.


Abstract-- In this study, basalt stone availability as storage material in the sensible heat storage method and the effect of heat transfer fluid flow rate were investigated. The experiments were carried out at three different flow rates, and measurements were taken at intervals of ten minutes for three days for each flow rate. Analytical results also show that the heat transfer to the water at 15 L min-1 is 660.5 W on average. On the other hand, it was determined that the average amount of heat transferred by the fluid at 30 and 45 L min-1 is 2339.9 and 2626.3 W, respectively. These results revealed that the increase in the intake temperature caused an increase in the fluid amount of heat transferred. A multiple linear regression model was created to determine the mathematical relationship between the inlet temperature and flow independent variables. Fluid heat transfer dependent variable and heat transfer values calculated by the generated model are found linear. It is seen that the amount of heat stored by the heat storage material decreases with the increase of the water flow rate. As a result of the calculations made, the water flow's heat storage efficiency adjusted at 15, 30 and 45 L min- 1 was found 43.1%, 9.5% and 6.5%, respectively. According to these results, it is concluded that the water flow rate as low as possible in such heat storage systems will increase the efficiency of the heat storage. Besides, the volumetric heat storage capacity of basalt stone was determined as 3417.3 kJ m-3 oC-1.

Keywords-- sensible heat storage, basalt stone.

I. INTRODUCTION

Energy systems play a key role in harvesting energy from various sources and converting it to the energy forms required for applications in various sectors, e.g., utility, industry, building and transportation. Energy sources like fossil fuels can be used to provide energy according to customer demand, i.e. they are readily storable when not required. But other sources such as solar and wind energy need to be harvested when available and stored until needed (Koohi-Fayegh and Roses, 2020)

Although solar energy, which is the most widely used type of renewable energy source in practice, is one of the most promising alternative energy options for fossil fuels, the most important problem in using it as an energy source is the energy source's discontinuity. The energy output acquired on sunny days is typically upwards compared to the energy needed to counterbalance the instantaneous demand, whereas, on cloudy days, the solar energy is rather inadequate (Boonsu et al., 2016) Said inefficiency of solar energy leads to the fact that it cannot be utilized at high efficiency. For these reasons, it is very important to research and develop systems that can store energy efficiently and economically to obtain energy from solar energy systems on cloudy days and night hours when the energy input is insufficient (Dinçer and Rosen, 2011). Lately, quite a few methods are utilized for storing energy. However, because of its ease of application, the storage of heat energy obtained by conversion or cycle is the most used energy storage method (Kozak and Kozak, 2012).

The storage of heat energy is referred to as the temporary storage of heat energy at high or low temperatures. The basis of heat energy storage systems; consists of providing energy to the storage system, storing this obtained energy and using stored energy at the requested time. This situation is briefly; loading, storage, and recovery as processes can be summarized. Storage of heat energy; closing the location and time difference between using and obtaining energy provides more effective and efficient use of energy in heating and cooling systems and thus achieves significant energy savings. Heat storage techniques are in two forms; sensible heat and latent heat (Yılmazoğlu, 2010). Using Phase Change Material (PCM) as storage media for latent thermal energy is an effective way for using thermal energy. PCMs give a high energy storage capacity by absorbing or releasing latent heat during phase change process during isotherm conditions. So PCMs used in many studies with different types, shapes and place of them through the system. Many types are used such as paraffin wax, stearic acid, magnesium chloride hexahydrate, vegetable-based oil and lauric acid (Malkawi and Tamimi, 2021).

In sensible heat storage systems, energy is stored by utilizing the sensible heat generated due to changing the temperature of a storage medium like water, air, oil, rock beds, bricks, sand and soil (Dinçer and Rosen, 2011). Many of the storage materials used in sensible heat storage systems are abundant and generally inexpensive. Besides, the technology developed in order to be used to store heat energy from these storage materials is suitable for use in efficient systems. For these reasons, sensible heat storage is preferred as the most used heat storage application at present. In the storage of heat energy using this method, the storage material's temperature changes during the storage and recovery of heat. An alluring property among the rest is the effectuation of a vast number of heat storage and recovery cycles (Öztürk, 2015).

There are several studies in the literature regarding the application of sensible heat storage systems. In one of the studies for this purpose, although the outdoor temperature decreased in winter, the indoor temperature was kept at 13°C using the packed bed heat storage system (Arizov and Niyazov, 1980). In another study carried out in two different greenhouses, it was determined that a temperature difference of 10°C occurred at night between the greenhouse where the storage system is located and the other greenhouse (Kürklü et al., 2003). In another study, when the sensible heat storage method was used in the greenhouse, it was determined that greenhouse agriculture would reduce the heating costs, which had a large share in the total production expenses. As a result of the calculation, 60-70% savings would be accomplished with the utilization of the so-called method from the amount of coal needed for greenhouse heating applications was found (Öztürk, 2012). In the studies carried out in the proper design of heat energy storage systems, it was determined that the sensible heat storage method is more advantageous than the latent heat storage method compared to design, construction, cost and ease of operation (Khare et al., 2013) In another study, experiments were carried out to select the best storage material among five types of rock species (quartz, basalt, granite, hornfels and marble) abundant in Morocco. As a result of the experiments, it was explained that the use of these rocks as a storage material in the sensible heat storage system increases the efficiency and reduces the cost of the system (Grirate et al., 2014)

In this study, basalt stone's usability as a heat storage material in the sensible heat storage method was investigated. The effect of the flow rate of the heat transfer fluid on the efficiency of heat storage was investigated in these systems. For this purpose, the flow rate was adjusted to 15, 30 and 45 L min-1.

II. METHODS
A. Storage Material

Approximately 2.5 tons of basalt stones were used as heat storage material in our study (Fig. 1). The reason for using basalt stone in our study is that it is one of the most common rock types on earth. On the grounds of its immense resistance to abrasion and climatic circumstances, it is commonly the favored natural stone as a base and superstructure material. Basalt used as the heat storage material was provided from the Toprakkale district of the Osmaniye province in Turkey. Toprakkale basalt is spread over an area of approximately 115 km in quaternary plateau basalts between Toprakkale and Erzin districts and the Gulf of İskenderun. Toprakkale basalts are seen as massive, black-gray colored, large-small and angular blocks. The basalt stone's physical and thermal properties are given in Table 1.

B. Heat Storage System

The already stated study was designed for day-to-day storing of solar energy with sensible heat storage with the utilization of basalt stone and operated in the Tayfur So-

Figure 1: Basalt stone used as heat storage material in the study.

Figure 2: Schematic representation of solar thermal storage system (P:Pump; V:Throttle Valve; F:Flowmeter; ST: Tempera-ture sensor).

 

 

Table 1. Physical and thermal properties of basalt (Eppelbaum et al., 2014)

 

men Campus of Hatay Mustafa Kemal University in Turkey. The schematic view of the experimental setup was given in Fig. 2.

The heat transfer fluid from the solar collectors was transferred to the heat storage system, as in Fig 2. The heat carried by heat transfer fluid circulated in the storage tank was absorbed and stored by basalt stones in the heat storage system. Subsequently to the absorption of heat carried with the means of a fluid, the cooled fluid was transferred back to solar collectors. Thus, the heat transfer fluid's continuous circulation between the heat storage unit and solar collectors was ensured.

Two standard flat plate liquid solar collectors with the same characteristics were used in the study. As a heat storage unit, the storage tank (Fig. 3) with a volume of 1 m3 in square prism shape made of corrosion-resistant galvanized, sheet material was used. Besides, with the purpose of implementing thermal insulation, glass wool was situated on the exterior surface of the storage tank.

Corrugated polyethylene (PE) pipes with a 1-inch diameter were used to circulate the heat transfer fluid in the

Figure 3: Isometric (a), top (b) and right (c) views of the heat storage unit

heat storage system. In addition, a data logger to record the measured data, a flow meter with a measurement range of 6-60 L min-1 for flow measurement and a 3-stage circulation pump to circulate heat carrier liquid in a heat storage system was used.

The temperature was measured from points where heat transfer fluid entered the heat storage tank and exited from the heat storage tank. In addition, the temperature was measured from inside the tank in order to measure the temperature of the basalt stone. Temperature measurements carried out from 3 points were recorded via the data logger at 10-minute intervals. When evaluating the obtained data, the cases where the difference between inlet and outlet temperature of the heat transfer fluid to the storage system is negative were not considered because the discharge system was not installed in the experiment.

The changeable throttle valve ensured the flor rate needed for the circulation of the heat transfer fluid at various flow rates. Flow measurements with the flow meter were carried out by throttling the valve until the system reached the desired flow rate. The experiments were performed in three different flow rates as 15, 30 and 45 L min-1.

In the heat storage system, Eq. 1 was used to calculate the amount of heat transferred by the water, which is the heat transfer fluid and the specific heat of the water was taken as 4.18 kJ kg-1 oC-1 (Çengel, 2006)

. (1)

The amount of heat stored by basalt stones was calculated by Eq. 2 using the lowest and highest temperature differences obtained due to the temperature measurements carried out within the heat storage tank. In this calculation, the mass of basalt stone and specific heats were 2500 kg and 1.23 kJ kg-1 oC-1, respectively.

.                                    (2)

Using the ratio of the amount of heat stored by basalt stones to the amount of heat carried by the heat transfer fluid to the heat storage system, the system's efficiency was calculated as in Eq. 3.

                     (3)

The volumetric heat capacity of basalt stone was calculated using Eq. 4, which is the ratio of highest and lowest temperature difference measured in the heat storage tank to amount of heat stored by basalt stones, and the volume of the tank was taken as 0.9 m3.

              (4)

Statistical analyzes were performed by using IBM SPSS 20 statistics program to determine the relationships between measured data and calculated stored heat quantities. The effect of water flow rate on the amount of heat stored was determined by analysis of variance. In addition, the Duncan test was used to determine whether the flow change had a statistically significant effect on the amount of heat stored. For the identification of the relationship between the inlet temperature and the amount of heat stored, an analysis was conducted among the stated two data. Finally, regression analysis was formed between water flow rate, inlet temperature and stored temperature.

III. RESULTS

A. Measurements at Different Water Flows

When the flow rate was set at 15 L min-1, the graphs of the measurements obtained at 10 minutes intervals on 29-30 April and 2 May 2017 were given in Fig. 4. As a result of the measurements carried out at the water flow rate set at 15 L min-1, the heat transferred was increased depending on the inlet temperature of water to the storage tank. Besides, the temperature difference in the storage all over the daytime was determined to be in a spectrum of almost 6 °C. The highest temperatures (38 oC) in the storage were measured after midnight. Simultaneously, it was determined that the water temperature entering the tank was lower than the leaving water temperature and the heat storage system lost heat.

Figure 4: Measurements obtained at 15 L min-1 water flow rate.

 

Figure 5: Measurements obtained at 30 Lmin-1 water flow rate.

When the flow rate was set at 30 L min-1, the graphs of the measurements obtained at 10 minutes intervals on 25-26 and 27 May 2017 were given in Fig. 5. As a result of the measurements carried out at the water flow rate set at 30 L min-1, the heat transferred was increased depending on the inlet temperature of water to the storage tank. Additively, the temperature difference in the storage all over the daytime was determined to be in a spectrum of almost 6 °C. The highest temperatures (40 °C) in the storage were measured after midnight.

As a result of the measurements carried out at the water flow rate set at 45 L min-1, the heat transferred was increased depending on the inlet temperature of water to the storage tank and given in Fig. 6. In addition, it was determined that the temperature change in the storage throughout the day was in a range of approximately 5 °C. The highest temperatures (42 °C) in the storage were measured after midnight.  At the flow rate set at 45 L  min-1, it was observed that the difference between the inlet and outlet temperatures of the water was higher than the differences in the other flow rates. At the noontime, notably, a temperature change of about 2 °C was observed, and by virtue of the aforementioned temperature contrast, the extent of heat transferred at a flow rate of 45 L min-1 was remarkably above with respect to the values acquired at a flow rate of 15 L min-1. On the other hand, it was determined that the amount of heat transferred at a flow rate of 30 L min-1 was approximately the same.

 

Figure 6: Measurements obtained at 45 Lmin-1 water flow rate.

Figure 7: Amount of heat stored and heat storage efficiency.

B. Heat Storage Quantity and Efficiency

The heat storage amount of the basalt stone used as heat storage material in the system and the system's storage efficiency were calculated and given in Fig. 7 and Table 2.

As a result of the experiments and calculations, it was determined that the flow rate affects the amount of heat storage. It has correspondingly realized that the development of the heat transfer fluid flow rate diminished the heat storage performance of the storage material.

C. Volumetric Heat Capacity

The values obtained using the calculated heat storage amount and the measured temperature differences are given in Table 3.

 


Table 2 Heat storage data at different water flow rates

 

15 L min-1

30 L min-1

45 L min-1

Day 1 measurement (kJ)

19289.48

18997.35

12619.80

Day 2 measurement (kJ)

16878.68

17109.30

13978.95

Day 3 measurement (kJ)

16119.15

16236.00

12619.80

Average heat storage (kJ)

17429.10

17447.55

13072.85

Average heat transferred to water (kJ)

40433.76

183475.20

200378.54

Heat storage efficiency of the system (%)

43.11

9.50

6.52

 

Table 3 Volumetric heat capacity of basalt stone at different water flow rates

 

15 L min-1

30 L min-1

45 L min-1

Day 1 measurement (kJ m-3 oC-1)

3418.30

3416.79

3417.22

Day 2 measurement (kJ m-3 oC-1)

3416.73

3417.07

3417.83

Day 3 measurement (kJ m-3 oC-1)

3417.97

3416.66

3417.22

Average (kJ m-3 oC-1)

3417.66

3416.83

3417.42

 


Table 4 Volumetric heat capacity of some materials (Engine-ering Toolbox, 2017)

As a result of the measurements and calculations, the basalt stone's average volumetric heat capacity was determined as 3417.30 kJ m-3 oC-1 in all water flow rates. Immediately upon comparing the volumetric heat capacities with the storage materials given in Table 4, the fact of the basalt stone being one of the materials having the best storage capacity as storage material was apparent.

D. Statistical Analysis

The effect of water flow rates of 15, 30 and 45 L min-1 on the transferred heat quantity () was determined by analyzing variance. The measurement values with a negative difference between the inlet and outlet temperature with inside the analysis were not utilized.

As a result of the analysis using the data obtained from the measurements made at each water flow rate, the average value of the heat transferred at a 15 L min-1 was determined to be 660.5 W. On the other hand, the average amount of heat transferred by heat transfer fluid measured at flow rates of 30 and 45 L min-1 (2339.9 W and 2626.3 W) was found to be close to each other (Table 5). Upon the examination of the variance analysis table, it is apparent that the relationship between the water flow rate and the amount of heat transferred by the fluid is statistically notable. Correlation analysis results to determine the relationship between water flow rate, water inlet temperature and transferred heat are given in Table 6.


Table 5 Analysis results of variance between water flow rate and transferred heat (r)

 

Table 6 Correlation analysis between flow, inlet temperature and transferred heat

**. Correlation is significant at 0.01 (two-tailed test).

 

Table 7 Results of regression analysis

 


Correlation analysis results showed a strong linear relationship (0.714) between water inlet temperature and the amount of heat transferred. This relationship shows that an increase in inlet temperature leads to an increase in the fluid amount of heat transferred.

The purpose of the last phase of the statistical analysis was to specify the mathematical relationship between the inlet temperature and the quantity of heat transferred by the fluid. For this purpose, regression analysis was performed, and a multiple linear regression model was created. The analysis results are given in Table 7.

When the regression analysis results were examined, a multiple linear regression model giving the amount of heat transferred by the fluid was formed as in Eq. 5.

               (5)

where  is the amount of heat transferred by the fluid (W),  is the Inlet temperature of fluid (oC) and  is the Fluid flow rate (L min-1).

In the created model, the coefficient of determination (R2) was calculated as 0.772.

V. CONCLUSIONS

The following results were obtained in this study to investigate the usability of basalt stone as a heat storage material in a sensible heat storage method. It has been found that the heat transferred by the heat transfer fluid increases depending on the inlet temperature of the fluid into the tank. It has been noticed that the interior temperature of the tank began to increase at the time that the inlet temperature of the heat transfer fluid began to decrease. The temperature increase in the tank for all tests was in the range of about 4-6 °C. After midnight, when the system began to lose heat, the tank's temperatures reached about 40 °C. In times more benefited from sunlight; at the water flow rates of 30 and 45 L min- 1, the difference between the inlet and outlet temperatures of the heat transfer fluid was almost the same (about 2 °C). Nevertheless, at the same hours, in flow rate adjusted as 15 L min-1 was observed that the heat transfer amount of fluid was lower than the other two adjusted flow rates due to the inlet and outlet temperature difference of the heat transfer fluid was low.

As a result of statistical analysis with the data obtained for each water flow rate, the amount of heat transferred for water flow rates of 15, 30 and 45 L min-1 were founded as 660.5 W, 2339.9 W and 2626.3 W, respectively. When the variance analysis table and Duncan multiple comparison test results were examined, it was found that the increase or decrease of water flow rate directly affected the amount of heat transferred by the heat transfer fluid. It was thus observed that the increase in the water flow rate triggered the increase in the amount of heat transferred by the heat transfer fluid.

When the graphs and correlation analysis results created with the data obtained from the measurements are analyzed, it was found that the water inlet temperature had a direct effect on the amount of heat transferred. In the graphs and analyses examined, it was seen that the amount of heat transferred increased with the increase of water inlet temperature. To determine the mathematical relationship between the inlet temperature and the amount of heat transferred by the fluid at different flow rates, regression analysis was performed, and a mathematical model was formed.

As a result of the measurements made at different flow rates, it was seen that the amount of heat stored by the heat storage material depends on the flow rate of the system. Subsequent to the tests, it was noticed that on the basis of the increase in the heat transfer fluid flow rate, the heat storage amount of the heat storage material, as well as the heat storage efficiency, had been decreased. This is the inability to effectively transferred heat carried by the fluid to the heat storage material because heat transfer fluid in high flow conditions was quickly circulated between storage materials and remained less time in the heat storage tank. Therefore, it was concluded that keeping the water flow rate as low as possible in such heat storage systems will increase heat storage efficiency.

Besides, when the calculated volumetric heat capacity of the basalt stone (3417.30 kJ m-3 °C-1) used in the study was compared with the other storage materials given in the literature, it was determined that the usability of the basalt stone as a storage material was appropriate.

In subsequent studies on heat storage, determining heat storage properties, especially in different materials that can be easily found in nature, such as basalt stone, will increase the material diversity.

ACKNOWLEDGMENTS

This article was prepared from the MSc study supported by Hatay Mustafa Kemal University Scientific Research Projects Coordinator (Project No: 15301).

NOMENCLATURE

          specific heat of basalt stone [kJ kg-1 oC-1]

           specific heat of water [kJ kg-1 oC-1]

               mass [kg]

               mass flow [kg s-1]

         heat storage of basalt stone [kJ]

        heat transferred by water [kJ s-1]

        volumetric heat capacity of basalt stone [kJ m-3 oC-1]

          temperature (oC)

         the volume of storage tank [m3]

          heat storage efficiency [%]

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Received: October 19, 2021

Sent to Subject Editor: November 22, 2021

Accepted: January 11, 2022

Recommended by Subject Editor Gianfranco Caruso